Any of the Butterfly Effect movies are pretty good watching. All quite different - I enjoyed them equally.
'
en.wikipedia.org/wiki/Moon_%28film%29:jiy4birf' is excellent imho.
Also, have you watched 'Misfits'? Not a film but watched recently and was impressed.
If you wanting something totally out-there oddball some interesting thinking 'films'...
On a pyschological/philosphical level '
en.wikipedia.org/wiki/Timothy_Treadwell:jiy4birf' is a film/documentary worth seeing about a strange man who lived with grizzly bears for some crazy amount of years (13!), before the bears ate him.
Some really interesting 'art' movies about the planet/life are breathtaking such as '
en.wikipedia.org/wiki/Baraka_%28film%29:jiy4birf' (
must be on Blu-ray), and the third in a series of music/imagery 'films' called
en.wikipedia.org/wiki/Naqoyqatsi:jiy4birf. The other two of the series are slightly older (look dated) but are still utterly amazing if you can stand them.
I'd agree with the other recommendations here - I'll add some more in a bit but my brain is fried.